TGA files and variables summary

This reference section provides a summary of files and variables related to TGAs and the LI-6800.

Calibration files

Calibration files include information describing the calibration tanks and adjustments made during a calibration.

Tank files

These describe the sources of calibration gas. Tank files are saved in the home/licor/logs/tga/tanks directory. They contain a json map, with gas names as keys. They are created when you do the procedure described in Adding tanks. Listing 12‑1 shows an example added by the +CO2 Iso Tank button, and Listing 12‑2 a tank added by the +Other Tank button.

Listing 12‑1. Example tank file (CO2_1000_-30_dO18_-12_dO17_-4.json).

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{
    "CO2": 1000,
    "dC13": -29.7,
    "dO17": -3.5,
    "dO18": -12.1,
    "C12": 984.3714,
    "C13": 10.733,
    "O18": 4.0617,
    "O17": 0.7751
}

Listing 12‑2. Example tank file (ch4_2ppm_N2O_0ppm). Tanks added by +Other Tank carry explicit units.

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{
      "CH4”: {
            "value": 2.07, 
            "units": “ppm"
      }, 
      "N2O": {
            "value": 0.355, 
            "units": “ppm”
      }
}

Tank Measurement (TM) Files

TM files are saved in the home/licor/logs/tga/tanks/events/<serial> directory. They are created manually by tapping the Capture button (Figure 12‑45), or under program control (Capturing a Tank Measurement).

Listing 12‑3. Example TM file.

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{
    "id": "TM0171",
    "time": "2025-08-12 14:20:49",
    "tank_name": "1000_-30_-4_-12",
    "tank_on_secs": "01:56", //How long the tank has been on (minutes:seconds)
    "tank_cal": {             //The associated tank cal file
        "CO2": 1000,
        "dC13": -29.7,
        "dO17": -3.5,
        "dO18": -12.1,
        "C12": 984.3714,
        "C13": 10.733,
        "O18": 4.0617,
        "O17": 0.7751
    },
    "deltas": {             //Measured (from data, below) - true (from tank_cal, above)
        'CO2': -0.1,
        'dC13': -0.02,
        'dO18': -0.04,
        'dO17': -0.34,
        'C12': -0.0407,
        'C13': -0.0006,
        'O18': -0.00039,
        'O17': -0.00024
    },
    "tga_cal": {             //The TGA cal at time of measurement
    "sn": "TG25-01057",
        "latest_atm": "ATM0099",
        "Offset_Cal_C12": 0.42998502194008736,
        "Offset_Cal_C13": 0.12068877735539418,
        "Offset_Cal_O18": 0.027400889754766827,
        "Offset_Cal_O17": -0.0014,
        "C12_Span": 1.0172029290401823,
        "C13_Span": 1.0162836221967664,
        "O18_Span": 1.0084701300925054,
        "O17_Span": 0.9331608051073214
    },
    "data": {                 //The TGA_stats group at time of measurement
        "period": 40,
        "H2O": -55.893053724999994,
        "H2O_sd": 5.764644894481073,
        "H2O_slp": -27.75925959600212,
        "CO2": 999.9481739999999,
        "CO2_sd": 0.09683552049221775,
        "CO2_slp": 0.15798184497769227,
        "C12": 984.3306964999999,
        "C12_sd": 0.09626425898406533,
        "C12_slp": 0.1568479280658279,
        "C13": 10.732370575000001,
        "C13_sd": 0.000733651718716026,
        "C13_slp": 0.0007457044104302504,
        "O17": 0.77485919525,
        "O17_sd": 0.0006381489733478628,
        "O17_slp": -0.00032163199721669346,
        "O18": 4.061307247499999,
        "O18_sd": 0.0006038512660363844,
        "O18_slp": 0.0006815634458901812,
        "NH3": 12.745961175,
        "NH3_sd": 0.4807668507578745,
        "NH3_slp": -1.0440158893188,
        "dC13": -29.720341025000003,
        "dC13_sd": 0.09419300619565346,
        "dC13_slp": -0.13454599382645405,
        "dO17": -3.8357486775,
        "dO17_sd": 0.7658243307591981,
        "dO17_slp": -0.5950952046825331,
        "dO18": -12.140916375,
        "dO18_sd": 0.13636244665865435,
        "dO18_slp": -0.07630746304904867
    }
}

Applied Tank Measurement (ATM) Files

ATM (applied tank measurement) files are saved in the home/licor/logs/tga/tanks/events/<serial> directory. They are created manually (Figure 12‑45) when one or more tank measurements are actually used to update a TGA calibration, or under program control (Capturing a Tank Measurement).

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{
    "events": [ //The list of TM events used.
        "TM0257 @ 15:42 Diffs: CO2=-0.1ppm \u03b4C13=0.93\u2030",
        "TM0258 @ 15:43 Diffs: CO2=0.0ppm \u03b4C13=0.17\u2030"
    ],
    "tga_cal": {//The TGA cal before being changed by this ATM
    "sn": "TG25-01057",
        "latest_atm": "ATM0100",
        "Offset_Cal_C12": 2.8499671464940115,
        "Offset_Cal_C13": 0.07463568343094369,
        "Offset_Cal_O18": 0.019001373117769792,
        "Offset_Cal_O17": -0.005281035583985035,
        "C12_Span": 1.0134588381927159,
        "C13_Span": 1.019549060440458,
        "O18_Span": 1.0093372871121618,
        "O17_Span": 0.9364494128364119
    },
    "spans": {     //The new TGA spans (always present)
        "C12": 1.013185180680767,
        "C13": 1.0195958329492814,
        "O18": 1.0095267746387697,
        "O17": 0.9371846109860461
    },
    "offsets": {//The new TGA spans (only present for multi-TM calibrations)
        "C12": 3.102881001341697,
        "C13": 0.07296212684004466,
        "O18": 0.017842448264632153,
        "O17": -0.006202159560105282
    },
    "meas": {     //TGA measurements of the tanks, extracted from the TM files
        "C12": [
        393.63955533333336,
        984.4218803333334
        ],
        "C13": [
        4.296139016666666,
        10.735643600000001
        ],
        "O18": [
        1.62573474,
        4.062277316666667
        ],
        "O17": [
        0.3111086056666666,
        0.7757438246666666
        ]
    },
    "tank": {     //True values, extracted from the tank values in the TM files
        "C12": [
            393.7486,
            984.3714
        ],
        "C13": [
            4.2932,
            10.733
        ],
        "O18": [
            1.6247,
            4.0617
        ],
        "O17": [
            0.3101,
            0.7751
        ]
    },
    "labels": { //Prompts used for the Implement? dialog.
        "C12": "Set C12 span to 1.013185, offset to 3.102881",
        "C13": "Set C13 span to 1.019596, offset to 0.072962",
        "O18": "Set O18 span to 1.009527, offset to 0.017842",
        "O17": "Set O17 span to 0.937185, offset to -0.006202"
    },
    "action_list": { //Check box settings from the Implement? dialog
        "C12": true,
        "C13": true,
        "O18": true,
        "O17": true
    },                 //Used for the dialog, if any
    "header_text": "TM0257 @ 400 Diffs: CO2=-0.1ppm \u03b4C13=0.93\u2030, \u03b4O18=0.82\u2030\nTM0258 @ 1000
    Diffs: CO2=0.0ppm \u03b4C13=0.17\u2
}